I've found a few bits of software that suggest they might do this - but they either
refuse to compile, or don't seem to work properly. Has anyone got any suggestions?
Write one. You're best off picking a nice, simple instruction set (Z80 should be perfect). I remember doing this as a first-year undergraduate exercise - I think we wrote the simulator in C++ and simulated 6800 assembly, but really any language/instruction set will do.
The idea of "learning assembly language" these days is to get the idea of how computers work at the lowest level, only a select few (compiler writers, etc.) have any real reason to actually be writing assembly code these days. Modern processors are stuffed full of features designed to be used by compilers to help optimise code for speed/concurrent execution/power consumption/etc., and trying to write assembly by hand for a modern processor would be a nightmare.
Don't fret about getting your application production-ready unless you want to - in all likelihood the bits of software you've found so far were written by people exactly like you who wanted to figure out how assembly works and wrote their own simulator, then realised how much work would be involved in getting it "production ready" so the general public could use it.
