I have used Owin in the past to create a token endpoint in my Mvc Web Api projects to provide oauth 2.0 tokens with \"Resource Owner Password Credentials\" grant type w
Here is a pretty good walkthrough of how to use Active Directory Federation Services to obtain an OAuth2 token. https://technet.microsoft.com/en-us/library/dn633593.aspx. You'll have to follow all the links at the bottom to get the entire walkthrough.
Note that it refers to using Windows Azure AD Authentication Library for .NET. But according to that documentation, that library is used for both Azure Active Directory and on premises Active Directory.
As for the workflow, once authenticated you'll be able to obtain and present a bearer token to your WebAPI. Your WebAPI then "validates the signature of the token to ensure it was issued by AD FS, checks to see if the token is still valid and hasn’t expired and may possibly also validate other claims in the token. At this point, the client is either authorized and the information they requested is sent in the response or they are unauthorized and no data will be sent." - https://technet.microsoft.com/en-us/library/dn633593.aspx
You could use ADFS 3.0 on top of AD which would provide you with OAuth 2.0 Authorization Server functionality: http://blog.scottlogic.com/2015/03/09/OAUTH2-Authentication-with-ADFS-3.0.html
Putting the token endpoint behind "basic authentication" does not help you because you'd be authenticating the client on the token endpoint, not the user. You could put the authorization endpoint behind "basic authentication" though.