I would suggest having a look at Erlang - it's been getting a bit of press recently, so some of the learning resources are excellent. If you've used OO and/or procedural languages, Erlang will definitely bend your mind in new and exciting ways.
Erlang is a pure functional language, with ground-up support for concurrent, distributed and fault-tolerant programs. It has a number of interesting features, including the fact that variables aren't really variables at all - they cannot be changed once declared, and are in fact better understood as a form of pattern.
There is some talk around the blogosphere about building on top of the Erlang platform (OTP) and machine support for other languages like Ruby - Erlang would then become a kind of virtual machine for running concurrent apps, which would be a pretty exciting possibility.
