I know of one smallish company that have sent a mail server product to the market. They had at least 2 people working full time on the project.
Also, a major player in the IT business have several employees using D in larger internal projects.
Further I know of one company seeking venture funding, several (at least 4) employees in smaller companies using D either part or full time, and at least a couple (including me) actively seeking opportunities in the consulting market.
I've probably left out a few that I should have known about, and probably some I haven't heard about, but that still exists, as the above is more or less those I know myself via the community.
A small percentage of my current income comes from D.