Start by reading The Zen of Python
You can read it at the link above, or just type import this
at the Python prompt. =)
Take advantage of Python features not offered* by C#
Such as duck-typing, metaclasses, list comprehension, etc.*
Write simple programs just to test these features. You'll get used (if not addicted) to them in no time.
Look at the Python Standard Library
So you don't reinvent the wheel. Don't try to read the whole thing, even a quick look at the TOC could save you a lot of time.
* I know C# already has some of these features, but from what I can see they're either pretty new or not commonly used by C# developers. Please correct me if I'm wrong.