batch script with FOR does not work

Question

I need help with my script below:

It does not continue for the next row of machine.txt If I put the \")\" after \"echo !machine\", it shows the machines inside the machi

Answer 1

You cannot use goto within the for body as goto breaks the for loop context.

I would place your labelled sections :64bits and :32bits into sub-routines and call them:

@echo off
set server=\\server01\share

dir /B /O %server% | find "i32" | more +2 > 32.txt
FOR /F "tokens=*" %%A in (32.txt) do SET file32=%%A

dir /B /O %server% | find "i64" | more +2 > 64.txt
FOR /F "tokens=*" %%B in (64.txt) do SET file64=%%B

setlocal EnableDelayedExpansion

for /F "tokens=*" %%C in (machines.txt) do (
  set "machine=%%C"
  echo !machine!
  if exist "\\!machine!\c$\Program Files (x86)" (
    call :64bits
  ) else (
    if exist "\\!machine!\c$\Arquivos de Programas (x86)" (
      call :64bits
    ) else (
      call :32bits
    )
  )
  echo Finished !micro!
)
pause
endlocal
exit /B

:64bits
xcopy /D /Y /F /C %server%\%file64% \\!machine!\c$\
PsExec.exe -d \\!machine! "C:\%file64%" /q
exit /B

:32bits
xcopy /D /Y /F /C %server%\%file32% \\!machine!\c$\
PsExec.exe -d \\!machine! "C:\%file32%" /q
exit /B

Note: I did not check the purpose nor the logic of your script, I just fixed the for/goto issue.