To directly answer your question, no. PHP arrays can only contain one set of data for the key.
You need to use a multidimensional array, where the value of a key is an array with keys and values, e.g.:
$array = array
(
"bob" => array
(
"height" => "6.0",
"age" => "21",
),
"joe" => array
(
"height" => "5.9",
"age" => "35",
)
);
Here's a starting point for the basics
After that, there's a mountain of info already on Stack Overflow and the rest of the internet. Search for "php multidimensional array"
Search here on Stack