for this task no a good idea to use suprocess. just use python os module
try this::
In [12]: import os
In [13]: os.getcwd()
Out[13]: '/home/najeeb'
In [14]: os.chdir('/home/najeeb/Desktop/project/')
In [15]: os.getcwd()
Out[15]: '/home/najeeb/Desktop/project'
In [16]:
if now any problem you face please let me know!