You can add them as resources, but you won't be able to execute your "program.exe" directly from the resource, at this is a pure Qt system that the underlying OS won't understand.
What you would need to do at execution time is to copy it (with the .dll) from the resources to a temporary location and execute from there.
Obviously, as @webclectic pointed out, this is not a proper approach. Unless there are imperious reason to do that, the right way is to create a package (.msi, .rpm depending of the target OS) with those executables and deploy them that way.