Use swaplevel with sort_index for sorting MultiIndex
:
df = df.swaplevel(0,1, axis=1).sort_index(axis=1)
print (df)
ParentAuction Copart IAA \
AVG GrossProfit AVG PMV Loss% Sales AVG GrossProfit AVG PMV
Make
Acura 112.99 -15.53 36.46 96.0 NaN NaN
ParentAuction
Loss% Sales
Make
Acura NaN NaN