The MSDN Specification link that you have posted, If you read carefully you will find your answer under section G:
G. Using CAST and CONVERT with datetime data
The following example displays the current date and time, uses CAST to change the current date and time to a character data type, and then uses CONVERT display the date and time in the ISO 8901 format.
SELECT
GETDATE() AS UnconvertedDateTime,
CAST(GETDATE() AS nvarchar(30)) AS UsingCast,
CONVERT(nvarchar(30), GETDATE(), 126) AS UsingConvertTo_ISO8601 ;
GO
Here is the result set.
UnconvertedDateTime UsingCast UsingConvertTo_ISO8601
----------------------- ------------------------------ ------------------------------
2006-04-18 09:58:04.570 Apr 18 2006 9:58AM 2006-04-18T09:58:04.570
(1 row(s) affected)
You can clearly see the difference.
Update
Check this: http://blog.sqlauthority.com/2012/11/21/sql-server-display-datetime-in-specific-format-sql-in-sixty-seconds-033-video/