I realize this is almost a year old, but the answer was never accepted and I think I've found an alternate solution, that I thought would be good to document here.
In order to extend the functionality of the u8 through traits, instead of trying to extend ToHex, why not create a new trait?
trait MyToHex {
fn to_hex(&self) -> String;
}
impl MyToHex for u8 {
fn to_hex(&self) -> String {
format!("{:x}", *self)
}
}
then used like so
fn main() {
println!("{}", (16).to_hex());
}
This has the advantage that you don't have to wrap every u8 variable with a new and superfluous data type.
The disadvantage is that you still can't use a u8 in a external function (i.e std library, or one you have no control over) that requires the ToHex trait (Vladimir Matveev's solution works in this case), but from OP it sounds like all you want to do is extend u8 only inside your code.