At some point in a code one may add something like
[[NSNotificationCenter defaultCenter] addObserver:self selector:@selector(doSomething) name:@\"Hello\" obj
If you mean "testing for whether you've already registered as an observer for the notification", I don't think there's an easy way apart from posting the notification and seeing you get a callback (with possibly disastrous effects).
If there's a danger of a double-add, I usually use [[NSNotificationCenter defaultCenter] removeObserver:self name:foo object:bar]
before the add.
Registering for notifications does not happen on a queue.
Remove observer before adding it:
How to avoid adding multiple NSNotification observer?
For unit testing you should mock NSNotificationCenter as it is dependency.