If a table, data might be duplicated amount rows, and there is not primary key for every row,
can i add an column to be a primary key?
Yes. Add a new column and set it as the primary key with AUTO_INCREMENT
. Doing so will create a new column and automatically add a unique id for each row.
ALTER TABLE old_table ADD pk_column INT AUTO_INCREMENT PRIMARY KEY;
This is possible with ALTER TABLE (Assuming you have a column that you want to use as a PK)
ALTER TABLE table
ADD PRIMARY KEY(column)
Alternativly:
ALTER TABLE table
ADD your_pk_column INT(11) AUTO_INCREMENT PRIMARY KEY