After creating new Visual C# Console Application (.NET Framework 4.5), such project contains default App.config file.
It can be done using mapped config file ,
ExeConfigurationFileMap configFileMap =
new ExeConfigurationFileMap();
configFileMap.ExeConfigFilename = "App4.config"; // full path to the config file
// Get the mapped configuration file
Configuration config =
ConfigurationManager.OpenMappedExeConfiguration(
configFileMap, ConfigurationUserLevel.None);
//now on use config object
AppSettingsSection section = (AppSettingsSection)config.GetSection("appSettings");