I recently learnt Python and had very little programming experience before. I found that doing a little bit of Python first then diving into Django worked for me. USing Django, looking through its reference material and Googling individual problems when I needed the help was really good.
Django has a built in Development server for you to use a bit like xampp, however, to make things like installing Django, installing Python, installing plugins etc a lot easier, use a unix based OS. I am developing on Mac OS and I have had no problems. Most Linux distributions will be the same. I wouldn't want to try Django development on Windows, there are just too many hacks you need to do to get it working, plus, it is more difficult for when you then publish the site (on a unix server).
Learn some Python, there are some good books suggested here, but don't get too deeply stuck into it if your focus will be Django. Go and do the official Django tutorial and then Google around for one or two more.
I use a book called 'The Definitive Guide to Django'. It is great for learning Django in the first place, but after the first few chapters, I stopped following it and started my own projects instead. Now it is a really good reference book to have.
It takes a while, but its worth it. I started working at a company as a Django developer recently and it is great.
Good Luck!
