Use a JSON parser, like JSON.NET
string json = "{ \"Atlantic/Canary\": \"GMT Standard Time\", \"Europe/Lisbon\": \"GMT Standard Time\", \"Antarctica/Mawson\": \"West Asia Standard Time\", \"Etc/GMT+3\": \"SA Eastern Standard Time\", \"Etc/GMT+2\": \"UTC-02\", \"Etc/GMT+1\": \"Cape Verde Standard Time\", \"Etc/GMT+7\": \"US Mountain Standard Time\", \"Etc/GMT+6\": \"Central America Standard Time\", \"Etc/GMT+5\": \"SA Pacific Standard Time\", \"Etc/GMT+4\": \"SA Western Standard Time\", \"Pacific/Wallis\": \"UTC+12\", \"Europe/Skopje\": \"Central European Standard Time\", \"America/Coral_Harbour\": \"SA Pacific Standard Time\", \"Asia/Dhaka\": \"Bangladesh Standard Time\", \"America/St_Lucia\": \"SA Western Standard Time\", \"Asia/Kashgar\": \"China Standard Time\", \"America/Phoenix\": \"US Mountain Standard Time\", \"Asia/Kuwait\": \"Arab Standard Time\" }";
var data = (JObject)JsonConvert.DeserializeObject(json);
string timeZone = data["Atlantic/Canary"].Value<string>();