"Which editor/IDE for ...?" is a longstanding way to start a "My dog is too prettier than yours!" slapfest. Nowadays most editors from vim upwards can be used, there are multiple good alternatives, and even IDEs that started as C or Java tools work pretty well with Python and other dynamic languages.
That said, having tried a bunch of IDEs (Eclipse, NetBeans, XCode, Komodo, PyCharm, ...), I am a fan of ActiveState's Komodo IDE. I use it on Mac OS X primarily, though I've used it for years on Windows as well. The one license follows you to any platform.
Komodo is well-integrated with popular ActiveState builds of the languages themselves (esp. for Windows), works well with the fabulous (and Pythonic) Mercurial change management system (among others), and has good-to-excellent abilities for core tasks like code editing, syntax coloring, code completion, real-time syntax checking, and visual debugging. It is a little weak when it comes to pre-integrated refactoring and code-check tools (e.g. rope, pylint), but it is extensible and has a good facility for integrating external and custom tools.
Some of the things I like about Komodo go beyond the write-run-debug loop. ActiveState has long supported the development community (e.g. with free language builds, package repositories, a recipes site, ...), since before dynamic languages were the trend. The base Komodo Edit editor is free and open source, an extension of Mozilla's Firefox technologies. And Komodo is multi-lingual. I never end up doing just Python, just Perl, or just whatever. Komodo works with the core language (Python, Perl, Ruby, PHP, JavaScript) alongside supporting languages (XML, XSLT, SQL, X/HTML, CSS), non-dynamic languages (Java, C, etc.), and helpers (Makefiles, INI and config files, shell scripts, custom little languages, etc.) Others can do that too, but Komodo puts them all in once place, ready to go. It's a Swiss Army Knife for dynamic languages. (This is contra PyCharm, e.g., which is great itself, but I'd need like a half-dozen of JetBrains' individual IDEs to cover all the things I do).
Komodo IDE is by no means perfect, and editors/IDEs are the ultimate YMMV choice. But I am regularly delighted to use it, and every year I re-up my support subscription quite happily. Indeed, I just remembered! That's coming up this month. Credit card: Out. I have no commercial connection to ActiveState--just a happy customer.
