I just installed visual studio 2013 on windows 8.1
When i go to new project then in the windows visual studio is not showing web templates like web pages, MVC 3,4,5
The Express versions of Visual Studio come in flavors for desktop and web. It sounds like you might want Microsoft Visual Studio Express 2013 for Web. If you want the more full featured version, check out the commercial versions here.
There's also a few ways to get the commercial versions for free. If you're a small company, check out the BizSpark program. If you're a student, check out the DreamSpark program.
Both Web and Desktop can be installed at the same time. I have both installed on my Windows Server 2012 Box