This set comprehension works for the List of Lists to produce a set of tuples:
>>> {(tuple(e)) for e in a}
set([(1, 2), (1, 3)])
Then use that to turn it into a list of lists again with no duplicates:
>>> [list(x) for x in {(tuple(e)) for e in a}]
[[1, 2], [1, 3]]