For a brand new application, is it better to use WPF over Windows Forms? I used Windows Forms before but not much WPF. As far as I know, WPF is the successor to Windows Form
In your case, WPF makes sense. For me, it's an application by application choice because there are a lot of things you can do really well in Windows Forms (like rapid development of business applications). I'm using WPF to write a nice GUI for a media center application (personal project for a media console on my 50-inch plasma screen).
However, if I'm writing a data entry and display application, I typically go with Windows Forms for speed of development. The XAML editor is better in Visual Studio 2010 but still has a way to go. Without a reference there's no IntelliSense help on a lot of the property attributes so it's impossible to know what goes in them (which is where I spend a lot of my time trying to find those values, either through a book or examples on the web). That said, if you do WPF write, you can make some very compelling user interfaces.
We just went through this too… we started a move to WPF over WinForms. I think that these days it is a pretty easy decision to put WinForms behind you. The tooling is getting better and better and if you can get a true designer on your team there are very few things that you can’t put together.
We are starting to realize that our future is actually not WPF, but it is Silverlight. As Silverlight matures it is becoming more and more on par with WPF and it allows you to run cross platform. The path of Silverlight is more like Adobe Air and one day it will live outside the browser (actually you can do it now, but it is a pain). I really think that the future for .NET UI is going to be Silverlight.
We dealt with this question about 9 months ago. We decided to go with WPF and so far we're happy with the decision. Yes, there is a learning curve. It's fairly considerable especially coming from WinForms where you have so much to unlearn. I also recommend you have access to a designer otherwise your application will probably look a bit shabby. Also be prepared for some WPF gotchas that will have you spending hours scratching your head saying 'why was this so hard'.
But WPF is a step ahead. The data binding, templating and complete control of how you want your windows to look makes you think that this how WinForms should've been originally.
Oh yes, and be prepared to shell out a couple of dollars for some missing controls. There are a couple of things missing like a Date picker and having checkboxes on tree controls (you can actually template this out, but it's not as simple as winforms in that regard). 3.5 SP1 includes a grid control now, thankfully.
I'm sure I'm missing a bunch more, but that's what I can come up with off the top of my head.
Good luck!
I found that once I got a handle on Expression Blend and WPF I was more productive at building UIs than with Windows Forms. To my mind that's one of, if not the, biggest factor with a new technology/tool; if you can't acheive the same result as the old tool faster with the new tool then all the bells and whistles, that you only use 10% of the time, won't make up for it.
Apart from that there are other advantages WPF has over Forms:
Having the interface in XAML makes it so much easier to fine tune all those obscure properties or to cut and paste a whole section of one control into another,
WPF makes it a lot easier to modularise an interface, breaking a screen down control by control. Forms can do the same to an extent but I always found it a battle,
Some of the bells and whistles are cool. I've found the use of animations (storyboards) really useful for data entry screens where you need different entry boxes depending on which product is chosen or such. With Forms you'd have to create a separate panel/form for each data entry screen, with WPF I use an animation to hide and move the various text boxes around.
In this case, I'd say follow the lead of your Vendor (i.e. Microsoft). Their own internal production increasingly features WPF; and it's scope (think Silverlight) and depth are clearly greater than WinForms. They also use it increasingly with reference to Best Practices. From all the evidence (here and elsewhere), it appears to be ready for Prime Time developement.
You have epressed no particular affinity for WinForms (I would guess what there is is based on familiarity). You'll need to switch eventually. A new project would be a great place to start the process, everything else being equal.
AFAIK WPF is the successor to WinForms, right?
I don't believe this is true as much as MS might like to push this. There is just too much legacy code written on Winforms for that to be a realistic thing in the near or even somewhat distant future.
So with that in mind, if you would like to, and can afford to spend the time learning WPF I would do that. Otherwise I would use Winforms.