http://www.w3.org/TR/selectors/
8.3.2. General sibling combinator
The general sibling combinator is made of the "tilde" (U+007E, ~)
character that separates two sequences of simple selectors. The
elements represented by the two sequences share the same parent in the
document tree and the element represented by the first sequence
precedes (not necessarily immediately) the element represented by the
second one.
example
h1 ~ pre
matches that <pre>
here:
<h1>Definition of the function a</h1>
<p>Function a(x) has to be applied to all figures in the table.</p>
<pre>function a(x) = 12x/13.5</pre>
There is also +
selector, for adjacent sibling combinator: with h1 + pre
the <pre>
tag would have to be right after <h1>