There is a ton of vertical market software developed in VB6 by manufacturers of various types of machinery. VB6 use of ActiveX controls, ActiveX DLLs, and the ability to consume most Win32 DLLs has lead to many manufacturers of various components to support VB6.
Using VB6 and the support libraries is at least an order of magnitude faster and more reliable than the older methods of assembly on custom chips, or using C. Note that even the C/C++ developers were helped as they can consume the new support libraries as well.
Many of these applications are filled with math functions that have been tested to work for the environment and the machinery they were designed for.
So when Microsoft made VB.NET incompatible with VB6 this was a BIG deal for many of us. Unlike the transition from VB3 to VB4-6, we have to touch our code in many place in order to get it working with .NET. So many in fact that it devolves to the same thing as rewriting your software in a new language.
For these reasons VB6 will live on for a while longer as all these machines are out there. Still needing new updates and fixes.