JPA : is just like an interface and have no concrete implementation of it to use functions which are there in JPA.
Hibernate : is just a JPA Provider which have the implementation of the functions in JPA and can have some extra functions which might not be there in JPA.
TIP : you can use
*combo 1* : JPA + JPA Provider(Hibernate)
*combo 2* : only Hiberante which does not need any interface
Combo 1 : is used when you feel that your hibernate is not giving better performance and want to change JPA Provider that time you don't have to write your JPA once again. You can write another JPA Provider ... and can change as many times you can.
Combo 2 : is used very less as when you are not going change your JPA Provider at any cost.
Visit http://blog-tothought.rhcloud.com//post/2, where your complete confusion will get clear.