on Leopard you can start a Local SMTP Server (Postfix) on OS-X Leopard
sudo vi /System/Library/LaunchDaemons/org.postfix.master.plist
before the closing tag at the end:
<key>RunAtLoad</key> <true/> <key>KeepAlive</key> <true/>
then start the thing with
sudo postfix start
now you check wheter the service is running with:
telnet localhost 25