Refer to openpyxl document, you can do changes as followings.
from openpyxl import Workbook
from openpyxl.drawing.image import Image
wb = Workbook()
ws = wb.active
ws['A1'] = 'Insert a xxx.PNG'
# Reload an image
img = Image(**r**'x:\xxx\xxx\xxx.png')
# Insert to worksheet and anchor next to cells
ws.add_image(img, 'A2')
wb.save(**r**'x:\xxx\xxx.xlsx')