I had something similar this evening which was driving me batty. Submitting a form was giving me the values in $_REQUEST but not in $_POST.
Eventually I noticed that there were actually two requests going through on the network tab in firebug; first a POST with a 301 response, then a GET with a 200 response.
Hunting about the interwebs it sounded like most people thought this was to do with mod_rewrite causing the POST request to redirect and thus change to a GET.
In my case it wasn't mod_rewrite to blame, it was something far simpler... my URL for the POST also contained a GET query string which was starting without a trailing slash on the URL. It was this causing apache to redirect.
Spot the difference...
Bad: http://blah.de.blah/my/path?key=value&otherkey=othervalue
Good: http://blah.de.blah/my/path/?key=value&otherkey=othervalue
The bottom one doesn't cause a redirect and gives me $_POST!