I don't think there is a way to do it directly but we can add in an additional column which will help us out
df2 <- structure(list(id = c("A", "B", "C", "A", "B", "C", "C"), cat = c("SS",
"SS", "SS", "SV", "SV", "SV", "SV"), val = c(220L, 222L, 223L,
224L, 225L, 220L, 1L)), .Names = c("id", "cat", "val"), class = "data.frame", row.names = c(NA,
-7L))
library(reshape2)
library(plyr)
# Add a variable for how many times the id*cat combination has occured
tmp <- ddply(df2, .(id, cat), transform, newid = paste(id, seq_along(cat)))
# Aggregate using this newid and toss in the id so we don't lose it
out <- dcast(tmp, id + newid ~ cat, value.var = "val")
# Remove newid if we want
out <- out[,-which(colnames(out) == "newid")]
> out
# id SS SV
#1 A 220 224
#2 B 222 225
#3 C 223 220
#4 C NA 1