GET and POST have two different purposes. From the Wikipedia HTTP entry:
GET
Requests a representation of the specified resource. Note that GET should not be used for operations that cause side-effects, such as using it for taking actions in web applications. One reason for this is that GET may be used arbitrarily by robots or crawlers, which should not need to consider the side effects that a request should cause. See safe methods below.
POST
Submits data to be processed (e.g. from an HTML form) to the identified resource. The data is included in the body of the request. This may result in the creation of a new resource or the updates of existing resources or both.
Basically, you should use GET to, well, GET information, and POST for any actions which alter the state of the server, such as adding new records.