I am using chrome version 36+
according to this page, I should be able to allow custom themes using the following instructions:
Installation Inst
I found it. There is a checkbox under experiments tab: Allow custom UI themes
These are some simple steps to follow, hope it will be helpful.
chrome://flags
Now select the experiment you want (e.g. "Allow custom UI themes").
You need to reload devtools after: Alt-R
will reload devtools itself, or you can just close and reopen it.