Nothing effective.
Depending on how much access you have to the computer the user is playing on, you can scan his process list for known chess programs and kick him if you see one... but there is no guarantee that he is actually using it in the manner you describe, and he can always use it on a separate computer if he has duel displays or a KVM.
Cheaters will find a way to cheat.
The good news in this case, is that the computer programs for chess are reasonably beatable unless they are running on some serious hardware.
Good luck.