For my current project (which runs on a relatively heavyweight process), I have adopted a peculiar form of TDD that consists of writing skeleton test cases based on requirements documents and GUI mockups. I write dozens, sometimes hundreds of those before starting to implement anything (this runs totally against "pure" TDD which says you should write a few tests, then immediately start on a skeleton implementation).
I have found this to be an excellent way to review the requirements documents. I have to think about the behaviour described in them much more intensively than if I just were to read them . In consequence, I find many more inconsistencies and gaps in them which I would otherwise only have found during implementation. This way, I can ask for clarification earlier and have better requirements when I start implementing.
Then, during implementation, the tests are a way to measure how far I've yet to go. And they prevent me from forgetting anything (don't laugh, that's a real problem when you work on larger use cases).
And the moral is: even when your dev process doesn't really support TDD, it can still be done in a way, and improve quality and productivity.