How does Windows protect against a user-mode thread from arbitrarily transitioning the CPU to kernel-mode?
I understand these things are true:
You're probably thinking that thread running in user mode is calling into Ring 0, but that's not what's actually happening. The user mode thread is causing an exception that's caught by the Ring 0 code. The user mode thread is halted and the CPU switches to a kernel/ring 0 thread, which can then inspect the context (e.g., call stack and registers) of the user mode thread to figure out what to do. Before syscall, it really was an exception rather than a special exception specifically to invoke ring 0 code.
If you take the advice of the other responses and read the Intel manuals, you'll see syscall/sysenter don't take any parameters - the OS decides what happens. You can't call arbitrary code. WinNT uses function numbers that map to which kernel mode function the user mode code will execute (for example, NtOpenFile is fnc 75h on my Windows XP machine (the numbers change all the time; it's one of the jobs of NTDll is to map a function call to a fnc number, put it in EAX, point EDX to the incoming parameters then invoke sysenter).