I\'ve created an ASP.Net MVC5 application, in which I have configured (and have working fine) Individual User Accounts via Google, Facebook, etc.
What I\'d like to do is
ACS can indeed be used, however as you have already implemented Google/Facebook signin I recommend that you directly integrate with Azure AD instead of going through an intermediate STS like ACS/thinktecture.
If your app' signin experience involves the user clicking on "Signin with Google/Signin with Facebook" stickers - you can add "Signin with your company' account." (there's even a recommended branding style: http://msdn.microsoft.com/en-us/library/azure/dn132598.aspx If you app performs realm discovery and forwards the user to the appropriate IdP (employing a text box saying something like "Enter your email address to sign in") - then you could add matching for your company name email addresses and forward those users to AAD.
In both cases, your application will issue an SSO request to SSO endpoint of AAD: https://login.windows.net/{company domain name/id}/{wsfed/saml/oauth2}. If you're using .Net, WSFed, this should see you through: http://msdn.microsoft.com/en-us/library/azure/dn151789.aspx. Look for the code:
SignInRequestMessage sirm = FederatedAuthentication.WSFederationAuthenticationModule.CreateSignInRequest("", HttpContext.Request.RawUrl, false);
result = Redirect(sirm.RequestUrl.ToString());
There's also an OpenIdConnect sample here: http://msdn.microsoft.com/en-us/library/azure/dn151789.aspx