Standard convex hull algorithms will not work with (longitude, latitude)-points, because standard algorithms assume you want the hull of a set of Cartesian points. Latitude-long
If all your points are within a hemisphere (that is, if you can find a cut plane through the center of the Earth that puts them all on one side), then you can do a central a.k.a. gnomic a.k.a. gnomonic projection from the center of the Earth to a plane parallel to the cut plane. Then all great circles become straight lines in the projection, and so a convex hull in the projection will map back to a correct convex hull on the Earth. You can see how wrong lat/lon points are by looking at the latitude lines in the "Gnomonic Projection" section here (notice that the longitude lines remain straight).
(Treating the Earth as a sphere still isn't quite right, but it's a good second approximation. I don't think points on a true least-distance path across a more realistic Earth (say WGS84) generally lie on a plane through the center. Maybe pretending they do gives you a better approximation than what you get with a sphere.)