We can see apple announcement here.. According to this doc, we can submit same binary with supporting 32-bit and also 64-bit. I found one stack overflow answer here. But Accordi
The program xcode 5 compiled contained two binary code:32-bit and 64 bit.In the 32-bit system will call the 32-bit code.In the 64-bit system will call the 64-bit code. At the same time, think about same program only have 32-bit code, the 64-bit system contained two framework:a 32-bit, a 64-bit.When the 64-bit system running the 32-bit program will call the 32-bit framework for the underlying support, running the 64-bit program will call the 64-bit framework for the underlying support.More detail you can see Apple's official documentation "64-Bit transition Guide for Cocoa Touch".
Use xcode 5 can be easily compiled program into 64.The basic procedure is as follow.
Set the support device into 'ios7'
The "Architectures" in "Build Setting" changed to "Standard Architectures (including 64-bit)".