Learn Python the hard way, exercise 10.2:
tabby_cat = \"\\tI\'m tabbed in.\"
persian_cat = \"I\'m split\\non a line.\"
backslash_cat = \"I\'m \\\\ a \\\\ cat.\"
The only reason you might need """
instead of '''
(or vice versa) is if the string itself contains a triple quote.
s1 = '''This string contains """ so use triple-single-quotes.'''
s2 = """This string contains ''' so use triple-double-quotes."""
If a string contains both triple-single-quotes and triple-double-quotes then you will have to escape one of them, but this is an extremely rare situation.