This is my web.config
mail settings:
//You can access the network credentials in the following way.
//Read the SmtpClient section from the config file
var smtp = new System.Net.Mail.SmtpClient();
//Cast the newtwork credentials in to the NetworkCredential class and use it .
var credential = (System.Net.NetworkCredential)smtp.Credentials;
string strHost = smtp.Host;
int port = smtp.Port;
string strUserName = credential.UserName;
string strFromPass = credential.Password;