Your question sort of has been answered in this question.
To add to that, the embedded processor industry is very segmented, it doesn't have a major player like Intel/x86 is for the "desktop" processor industry. The ARM processor does have a large share, so does MIPS I believe, and there are many smaller more specific microcontroller like chips available (like the MSP430 etc from TI).
As for documentation, I do embedded development for a day job, and the documentation we have access to (as software developers) is rather sparse. Your best bet is to use the documentation available on the processor manufacturers site.
