Lets have an example scenario:
Client opens a web site and finds the sum of two numbers which he enters from the textboxes.Then clicks on the ADD button.Two parameters a
In your case if you have User Interface for providing two numbers and then getting the result, it should be called a web application. But if you have an API exposed to receive two numbers and return result over http , then it should be called a web service.
At low level, both Web application and web service are kind of same thing. But the main point is that web services are for machine/program to machine/program communication whereas Web application is for Users.