When I ran git gui, I got this:
git gui
$ git gui git: \'gui\' is not a git command. See \'git --help\'. Did you mean one of these? grep init p
Edit your git config to an add an entry for gui in the alias section
nano ~/.gitconfig
[alias] gui = !sh -c '/usr/local/git/libexec/git-core/git-gui'
[alias]
gui = !sh -c '/usr/local/git/libexec/git-core/git-gui'
It looks like the path in the original answer is now obsolete. Updated instructions:
[alias] gui = !sh -c '/usr/local/opt/git/bin/git gui'
gui = !sh -c '/usr/local/opt/git/bin/git gui'