The best move I made was from Java to PHP.
Beware of complexity. Primarily, the key to great software is simplicity, and that is why PHP combined with a good framework kills Java.
With Java, you risk becoming a slave to your servlet container and framework. Choose the simplest most flexible framework. Controls and custom tags are the devil. You'll waste days learning things that were designed to make development quicker, but are ultimately too complex and inflexible. Java will slow development due to: complexity, compilation, and static types. You'll come to loathe null pointer exceptions.
Edit: Tools aside, Java and PHP are very similarly structured "C" style languages. Much more so than Python or Ruby. It is the static typing and complex tools that make Java so foreign.
