Im not sure if this is what you are looking for, but we write our main application with Java at the small company I work for, but have used python to write smaller scripts quickly. Backup software, temporary scripts to manipulate data and push out results. It just seems easier sometimes to sit down with python and write a quick script than mess with classes and stuff in java.
Temp scripts that aren't going to stick around don't need a lot of design time wasted on them.
And I am lazy, but it is good to just learn as much as you can of course and see what features exist in other languages. Knowing more never hurts you in future career changes :)
