I'm having a hardtime to see when I should or would use WCF. Why? Because I put productivity and simplicity on top of my list. Why was the ASMX model so succesful, because it worked, and you get it to work fast. And with VS 2005 and .NET 2.0 wsdl.exe was spitting out pretty nice and compliant services.
In real life you should have very few communication protocols in your architecture. This keeps it simple an maintainable. If you need to acces to legacy systems, write specific adapters for them so they can play along in the nice shiny and beautiful SOA world.