Thanks for asking
Please try the below it helps you if the bold area length isn't always 6 digits
DECLARE @document varchar(64);
DECLARE @start int;
DECLARE @lenght int;
SELECT @document = 'CMS/00014456582/693362/004535/JCR_110914_NEW_4535 CMS'
select @start = CHARINDEX('/',@document,CHARINDEX('/',@document)+1)+1
select @lenght = CHARINDEX('/',@document,CHARINDEX('/',@document,CHARINDEX('/',@document)+1)+1) - @start
select Substring(@document,@start, @lenght)