I was under the impression that \"int\" instruction on x86 is not privileged. So, I thought we should be able to execute this instruction from the user space application. But do
INT is a 'privilege controlled' instruction. It has to be this way for the kernel to protect itself from usermode. INT goes through the exact same trap vectors that hardware interrupts and processor exceptions go through, so if usermode could arbitrarily trigger these exceptions, the interrupt dispatching code would get confused.
If you want to trigger an interrupt on a particular vector that's not already set up by Windows, you have to modify the IDT entry for that interrupt vector with a debugger or a kernel driver. Patchguard won't let you do this from a driver on x64 versions of Windows.