from tkinter import *
root = Tk()
photo = PhotoImage(file=\'blueface.png\')
label = Label(root, image=photo)
label.pack()
root.mainloop()
The im
Older versions of tkinter can not handle .png's that well. Try making the file a .gif. Or use the PhotoImage from PIL:
import tkinter as tk
from PIL import Image, ImageTk
root = tk.Tk()
photo = ImageTk.PhotoImage(Image.open('blueface.png'))
label = tk.Label(root, image=photo)
label.pack()
root.mainloop()