Very general: Is there an easy way to tell which line of code last freed a block of memory when an access violation occurs?
Less general:
Yes!
Install the Windows Debugging Tools and use Application Verifier.
Now when you make the crash happen, you will get additional information in the debugger from AppVerifier. Use !avrf (may take a long time to run (minutes)) and it will try to give you as much useful information as possible.
You can all use the dps command on the memory address to get all the stored stack info (allocation, deallocation, etc).
You can also use the !heap command on the memory address:
0:004> !heap -p -a 0x0C46CFE0
Which will dump information as well.
Further Reading: