You are looking for the MERGE statement:
merge into ORDER_ATTRIBUTE ot
using (select ORDER_ID, CREATED_BY_NAME
from ORDER_APPROVALS
where PROCESS_DT is null) oa
on
(ot.ORDER_ID = oa.ORDER_ID)
when matched
and ot.ATTRIBUTE_ID = 123
then update set VALUE = oa.CREATED_BY_NAME;