I am working on a mobile mapping application (currently iOS, eventually Android) - and I am struggling with how to best support reverse geocoding from lat/long to Country/St
Radven
You will need to get the Shapefiles (lat/lng outline) of all the administrative entities (US states, countries, etc). There are a lot of public domain sources for these. For example, the NOAA has shapefiles for US states and territories you can download:
http://www.nws.noaa.gov/geodata/catalog/national/html/us_state.htm
Once you got the shapefiles, you can use a shapefile reader to test if a lat/lng is within a shape. There are open source readers in C, just google. I seen stuff at sourceforge for shapefiles, but have not used these myself.
The Team at OpenGeoCode.Org